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热处理对Ag-30Pd粉末相结构与形貌的影响 |
The Effect of Heat Treatment on Phases and Morphologies of Ag-30Pd Powders |
投稿时间:2015-07-29 |
DOI: |
中文关键词: 金属材料 银钯 粉末 热处理 相结构 形貌 |
英文关键词: metal materials silver-palladium powder heat treatment phase structure morphology |
基金项目:国家自然科学基金项目(51261008)、昆明市科技局高新技术研究与开发项目(2013-02-02-A-G-02-3040)。 |
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中文摘要: |
研究了热处理条件对不同方法制备的Ag-30Pd粉末的相结构与形貌的影响。结果表明,采用水合肼还原制备的Ag-30Pd共沉淀粉末,在335℃下经过油酸或氮气介质中液相或固相热处理后,粉末均朝合金化结构转变;采用抗坏血酸还原制备出的银钯合金粉初始为团聚颗粒,经400~450℃氮气气氛下热处理后,颗粒发生烧结而变得密实,结晶性提高;总体上,银钯共沉淀粉在335℃,合金粉在450℃的氮气保护下保温处理4 h后,粉末致密,粒径为1~3 μm,可更好地满足银钯浆料的使用要求。 |
英文摘要: |
The effect of heat treatment condition on phase structures and morphologies of the Ag-30Pd powders prepared by different methods were investigated. The results show that Ag-30Pd coprecipitated powders produced by the hydrazine hydrate as reducing agent can transform to Ag-30Pd alloy by 335℃ heat treatment under the condition of either oleic acid or nitrogen. The Ag-Pd alloy powders reduced by the oleic acid are composed of some agglomerated particles, and the density and crystallinity of the particles increases after heat treatment at 400~450℃. Overall, the Ag-30Pd powders with 1~3 μm particle sizes and high density after heat treatment under 335℃/ 4 h for coprecipitation powders, and 450℃/ 4 h for alloy powders can better meet the use requirements of electronic paste. |
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