文章摘要
晶体硅太阳能电池正面银浆的作用机制
The action mechanism of front silver paste upon crystal silicon solar cells
投稿时间:2021-06-28  
DOI:
中文关键词: 光伏电池  正面银浆料  电阻  光电转换
英文关键词: photovoltaic cells  front silver paste  resistance  photoelectricity exchange
基金项目:
作者单位E-mail
谭浩巍 昆明理工大学 材料科学与工程学院昆明 650093
深圳富邦新能源材料科技有限公司广东 深圳 518000 
thwaa12@sina.com 
谭富彬 昆明贵金属研究所昆明 650106  
梁琦 昆明理工大学 材料科学与工程学院昆明 650093  
陈亮维 昆明理工大学 材料科学与工程学院昆明 650093 elegantbaby@126.com 
虞澜 昆明理工大学 材料科学与工程学院昆明 650093  
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中文摘要:
      正面银浆由银粉、玻璃成分和粘合剂等组成,根据硅光伏电池的电阻构成、正面银浆各组分的特性对烧结时银浆料与硅基体的物理化学变化进行了分析。正面银浆选用密度高的球形银粉,Pb-Te系玻璃,烧结后栅线有足够大的高宽比,增加线条横截面积,使细栅线体电阻(Rf)达到最小值;烧结时还原生成铅和碲单质及其化合物,与硅基体形成共晶导电夹层,使前接触电阻(Rfc)达到最小值;硅太阳能电池的串联电阻(Rs)变小了,光电转换效率就得到提高。
英文摘要:
      The front silver paste consists of silver powder, glass composition and adhesive, etc. The physical and chemical changes between the silver paste and the silicon substrate during sintering were analyzed according to the resistance composition of the silicon photovoltaic cell and the characteristics of each component of the front silver paste. The front silver paste is made of high density spherical silver powder and Pb-Te glass. After sintering, the Grid line has a large enough height width ratio to increase the cross-section area of the lines, so that the fine grid wire resistance (Rf) can reach the minimum value. During sintering, lead and tellurium and their compounds are reduced, and forms an eutectic conductive interlayer with the silicon substrate to minimize the front contact resistance (Rfc). The series resistance (Rs) of the silicon solar cell becomes smaller, and its photoelectricity conversion efficiency is improved.
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