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ICP-AES法测定碘化铑中的铑含量 |
Determination of Rhodium in Rhodium Iodide by ICP-AES |
投稿时间:2015-03-25 |
DOI: |
中文关键词: 分析化学 碘化铑 ICP-AES 内标法 铑含量 |
英文关键词: analytical chemistry rhodium content rhodium iodide ICP-AES internal standard |
基金项目:云南省应用基础研究计划重点项目(2012FA006)。 |
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中文摘要: |
采用HNO3-HClO4消解样品除碘,王水溶解铑,以钇为内标,ICP-AES准确测定碘化铑中的铑含量。考察了样品消解处理和测定的最佳条件,并与硝酸六氨合钴重量法进行了比较,两者测定结果基本相符。方法精密度(RSD)<1%(n=11),加标回收率99.00%~101.14%。方法快速、简便。 |
英文摘要: |
An accurate quantitative analysis method of rhodium in rhodium iodide with inductively coupled plasma-atomic emission spectrometry (ICP-AES) was established. The sample, after the oxidation removal of iodine with HNO3-HClO4 and dissolving by aqua regia, was determined by ICP-AES using yttrium as an internal standard. The relative standard deviations (RSD) of the method was <1%(n=11) and the recovery was between 99.00%~101.14%. The method is accurate, rapid and simple compared with the classic hexaammine cobalt nitrate gravimetriy. |
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