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| 火焰原子吸收光谱法测定氧化铝催化剂中钯的不确定度评定 |
| Evaluation of Uncertainty for Determination of Pd in Aluminum Oxide Catalyst by FAAS |
| Received:June 04, 2012 |
| DOI： |
| 中文关键词: 分析化学 不确定度评定 火焰原子吸收光谱法 钯 氧化铝载体催化剂 |
| 英文关键词: analytical chemistry evaluation of uncertainty FAAS palladium aluminum oxidecatalyst |
| 基金项目: |
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| 中文摘要: |
| 对火焰原子吸收光谱法测定氧化铝催化剂中钯含量的不确定度进行了评定。对称重、消解、定容、标准工作溶液、标准曲线拟合等引入的不确定度来源进行了分析，并对各不确定度分量进行了量化和合成，得出消解过程和拟合校准标准曲线引入的相对不确定度分量是影响钯不确定度的主要分量，求得合成标准不确定度和扩展不确定度分别是21 g/t和42 g/t，并给出了测试结果:wPd±U(Pd)=(3021±42) g/t。 |
| 英文摘要: |
| The uncertainty for determination of Pd in aluminum oxide catalyst by FAAS was evaluated. The main influential factors of the uncertainty were determined, such as sample weighting, process of digestion, volume of test solution, standard solution, standard curve fitting. Each partial uncertainty of measurement was calculated and combined. It was indicated that the main source of uncertainty comes from the process of digestion and standard curve fitting. The standard uncertainty of 21 g/t and the extended uncertainty of 42 g/t were obtained, and the measurement result of wPd±U(Pd)=(3028±42) g/t was given. |
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