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| 固体亚硝酰硝酸钌的合成、结构及性质研究 |
| Synthesis, Structure and Properties of Solid Ruthenium Nitrosyl Nitrate |
| Received:February 22, 2013 |
| DOI： |
| 中文关键词: 有机化学 固体亚硝酰硝酸钌 负载型钌催化剂 合成 结构 性质 |
| 英文关键词: organic chemistry solid ruthenium(III) nitrosyl nitrate supported ruthenium catalyst synthesis structure properties |
| 基金项目:云南省院所技术开发专项(2011CF013、2012CF003)、云南省应用基础研究项目(2010ZC250)和云锡集团科技计划项目(2012-57A)。 |
| Author Name | Affiliation | E-mail | | CHANG Qiaowen | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | changqiaowen@126.com | | ZHOU Yan | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | YAN Caixian | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | SHEN Shanwen | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | ZHAO Jing | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | YE Qingsong | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | JIANG Jing | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | YU Juan | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | LIU Weiping | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | CHEN Jialin | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | cjl@ipm.com.cn |
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| 中文摘要: |
| 固体亚硝酰硝酸钌不含卤素、硫、磷等易引起催化剂中毒的元素，是制备用于煤化工行业的负载型钌催化剂的理想前驱体。以水合三氯化钌为原料，通过引入亚硝酰基、除去氯离子、萃取提纯制备了固体亚硝酰硝酸钌，适于固体亚硝酰硝酸钌的规模化合成生产。 |
| 英文摘要: |
| Ruthenium(III) nitrosyl nitrate is a relatively ideal precursor for preparing supported ruthenium catalysts used in coal chemical industry. The compound is free of harmful elements to the catalysts such as halogens, sulfur, phosphorus. A process involves introduction of nitrosyl, removal of chloride ions and extraction of the ruthenium nitrosyl product from the reaction system. The process is acceptable for large-scale production of solid ruthenium nitrosyl nitrate. |
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