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| 六水合三(2,2′-联吡啶)氯化钌(II)的合成及结构研究 |
| Synthesis and Structural Characterization of Tris(2,2′-bipyridyl)ruthenium(II) Dichloride Hexahydrate |
| Received:February 25, 2013 |
| DOI： |
| 中文关键词: 有机化合物 六水合三(2,2′-联吡啶)氯化钌(II) 合成 结构 |
| 英文关键词: organic compound tris(2,2’-bipyridyl)ruthenium(II) dichloride hexahydrate synthesis structure |
| 基金项目:国家院所技术开发专项(2013EG115008)、云南省院所技术开发专项(2011CF013、2012CF003)、云南省应用基础研究项目(2010ZC250)、云锡集团科技计划项目(2012-57A)。 |
| Author Name | Affiliation | E-mail | | CHANG Qiaowen | State Key Lab of Advanced Technologies for Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | changqiaowen@126.com | | JING Xiaoyu | State Key Lab of Advanced Technologies for Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | | | CHEN Jialin | State Key Lab of Advanced Technologies for Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | | | YAN Caixian | State Key Lab of Advanced Technologies for Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | | | YE Qingsong | State Key Lab of Advanced Technologies for Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | | | JIANG Jing | State Key Lab of Advanced Technologies for Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | | | YU Juan | State Key Lab of Advanced Technologies for Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | | | LIU Weiping | State Key Lab of Advanced Technologies for Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | liuweiping0917@126.com |
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| 中文摘要: |
| 以水合三氯化钌为原料，直接与2,2′-联吡啶反应，加入氯化钾，一步重结晶直接合成了高质量的六水合三(2,2′-联吡啶)氯化钌(II) [Ru(bpy)3Cl2.6H2O]。采用元素分析、核磁共振谱(13C、1H-NMR)、红外光谱(IR)和紫外可见光谱(UV-Vis)研究了Ru(bpy)3Cl2.6H2O的化学结构。研究使用的合成方法简单，具有产率高、纯度高的优点，适于规模化生产。 |
| 英文摘要: |
| High-purity tris(2,2′-bipyridyl)ruthenium(II) dichloride hexahydrate [Ru(bpy)3Cl2.6H2O] was synthesized by one step re-crystallization with KCl after the direct reaction of ruthenium(III) chloride hydrate with 2,2-bipyridine with a yield of 75%. This synthetic method is acceptable with respect to industrial manufacturing. The structure was confirmed by element analysis, 13C-NMR, 1H-NMR, IR and UV-Vis spectrum. |
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