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| 铱的氯桥双核配合物作为均相催化剂在有机合成中的应用 |
| Applications of Chloride-bridged Dimeric Complex of Iridium as the Homogeneous Catalyst in Organic Synthesis |
| Received:September 05, 2013 |
| DOI： |
| 中文关键词: 催化化学 1,5-环辛二烯氯化铱二聚体 ([Ir(COD)Cl]2) 均相催化剂 应用 机理 |
| 英文关键词: catalytic chemistry (1,5-cyclooctadiene) chloroiridium(I) dimmer ([Ir(COD)Cl]2) homoge- neous catalyst classification application reaction mechanism |
| 基金项目:国家科技支撑计划课题(2012BAE06B08)；国家院所技术开发专项(2013EG115008)；云南省院所技术开发专项(2012CF013)；云锡科技计划项目(2012-57A) |
| Author Name | Affiliation | E-mail | | ZHAO Jing | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | joywind.7@qq.com | | YAN Caixian | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | CHANG Qiaowen | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | LEI Jing | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | ZHANG Xianghui | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | YU Juan | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | JIANG Jing | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | YE Qingsong | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | LIU Weiping | State key Laboratory of Advanced Technology for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | liuweiping0917@126.com |
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| 中文摘要: |
| 铱的氯桥双核配合物—1,5-环辛二烯氯化铱二聚体[Ir(COD)Cl]2由于具有独特的催化性质，已作为均相催化剂，广泛应用于各类有机合成反应进行重要药品和精细化工产品的制备。这些反应包括烷基化反应，氢化反应，氧化反应及环加成反应。[Ir(COD)Cl]2催化剂具有适用底物范围广、原料易得，对映选择性高的优点。本文对[Ir(COD)Cl]2催化的反应类型、应用和相关的反应机理进行介绍和总结。 |
| 英文摘要: |
| (1,5-cyclooctadiene) chloroiridium(I) dimmer ([Ir(COD)Cl]2) is a newly developed homogeneous catalyst with great catalytic activity and good selectivity, and has been widely used in a wide variety of organic reactions involved in production of some important medicine and chemical reagents. The organic reactions include alkylation, hydrogenation, oxidation and cycloaddition. Herein, the applications of [Ir(COD)Cl]2 in organic synthesis and related catalytic mechanisms are introduced and discussed. |
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