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| 双[2-(对甲苯基)吡啶]乙酰丙酮合铱的合成及结构表征 |
| Synthesis and Characterization of [2-(p-tolyl)pyridine]2Ir(III)(acetylacetonate) |
| Received:September 19, 2014 |
| DOI： |
| 中文关键词: 金属有机化学 磷光材料 (tpy)2Ir(acac) 2-(对甲苯基)吡啶 乙酰丙酮 |
| 英文关键词: metal organic chemistry phosphorescence materials (tpy)2Ir(acac) 2-(p-tolyl)pyridine acetylacetone |
| 基金项目:国家院所技术开发专项(2013EG115008)；云南省院所技术开发专项(2012CF013)；云锡科技计划项目(2012-57A)。 |
| Author Name | Affiliation | E-mail | | HE Peilin | College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, China | hpl0907@qq.com | | YAN Caixian | State key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | ZHENG Ping | College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, China | | | CHANG Qiaowen | State key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | LIU Weiping | State key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | XIE Xiaotian | College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, China | |
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| 中文摘要: |
| 以水合三氯化铱为原料，2-(对甲苯基)吡啶作环金属配体、乙酰丙酮作辅助配体合成了双[2- (对甲苯基)吡啶]乙酰丙酮合铱[(tpy)2Ir(acac)]，通过质谱、氢谱、X射线单晶衍射分析表征手段确证了其分子结构。通过紫外可见光谱和光致发光光谱分析，研究了该配合物的光物理性能，在410和461 nm处有单重态和三重态吸收，在516 nm处有较强的绿光发射，表明该配合物是一种绿光材料。 |
| 英文摘要: |
| (tpy)2Ir(acac) was synthesized by the reactions of iridium chloride hydrate as the raw material, 2-(p-tolyl)pyridine as the cyclometallated ligand and acetylacetone as the auxiliary ligand, and the resulting complex was characterized by MS, 1H-NMR and single crystalline XRD. The absorption and emission spectra of the complex were measured to evaluate its photophysical properties. 1MLCT and 3MLCT absorptions occured at 410 and 461 nm, respectively, and a stronger photoluminescence appeared at 516 nm, indicating that this complex is a green material. |
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