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| Rh催化的[5+2]反应及其在有机合成中的应用 |
| Rh-Catalyzed [5+2] Cycloaddition Reaction and Its Applications in Organic Synthesis |
| Received:July 10, 2014 |
| DOI： |
| 中文关键词: 催化化学 Rh催化 [5+2]反应 有机合成 |
| 英文关键词: catalytic chemistry Rh catalysis [5+2] cycloaddition reaction organic synthesis |
| 基金项目:国家科研院所技术开发研究专项 (2014EG115007)、国家自然科学基金(51261008)、云南锡业集团科技计划项目(2013010504)。 |
| Author Name | Affiliation | E-mail | | ZHOU Limin | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | zlm@ipm.com.cn | | LIAO Xiali | Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming 650500, China | | | XU Ke | Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming 650500, China | | | CHEN Jialin | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | CHEN Liqiao | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | LI Junpeng | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals, Kunming 650106, China | lijunpeng@ipm.com.cn |
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| 中文摘要: |
| Rh催化的[5+2]反应是一类高效快速构筑多官能团化七元环的重要方法。介绍了常用的Rh催化剂及其配体；分别基于乙烯基环丙烷(VCP)和劳腾施特劳赫中间体类型的Rh催化[5+2]反应；Rh催化的[5+2]反应机理；Rh催化的[5+2]反应在复杂天然产物合成中的应用。 |
| 英文摘要: |
| The rhodium-catalyzed [5+2] cycloaddition reaction is an important methodology in rapid and efficient synthesis of a variety of multifunctional seven-membered ring. Introduced in this review were common rhodium-catalysts, catalyzed [5+2] cycloaddition reactions, the mechanism involved and potential applications in the synthesis of natural products. |
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