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| 大肠杆菌吸附某工业废水中Pt(IV)、Pd(II)的研究 |
| Adsorption of Pt(IV) and Pd(II) in Industrial Wastewater by Escherichia coli |
| Received:August 28, 2015 |
| DOI： |
| 中文关键词: 生物冶金 大肠杆菌E.coli 工业废水 吸附 Pt(Ⅳ) Pd(Ⅱ) |
| 英文关键词: biological metallurgy Escherichia coli industrial wastewater adsorption Pt(IV) Pd(II) |
| 基金项目:中国博士后科学基金(2013M531814)；中国博士后科学基金(2015T0880)；中南大学博士后基金；稀贵金属综合利用新技术国家重点实验室开放课题(SKL-SPM-201508)；国家自然科学基金项目(51104189)。 |
| Author Name | Affiliation | E-mail | | HE Jia | Key Laboratory of Biohydrometallurgy, Ministry of Education, School of Mineral Processing and Bioengineering, Central SouthUniversity, Changsha 410083, China | 1522921765@qq.com | | ZHAO Wenya | Key Laboratory of Biohydrometallurgy, Ministry of Education, School of Mineral Processing and Bioengineering, Central SouthUniversity, Changsha 410083, China | | | HE Min | Key Laboratory of Biohydrometallurgy, Ministry of Education, School of Mineral Processing and Bioengineering, Central SouthUniversity, Changsha 410083, China | | | LIU Xinxing | Key Laboratory of Biohydrometallurgy, Ministry of Education, School of Mineral Processing and Bioengineering, Central SouthUniversity, Changsha 410083, China | | | DONG Haigang | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of PlatinumMetals, Kunming Institute of Precious Metals, Kunming 650106, China | | | XIE Jianping | Key Laboratory of Biohydrometallurgy, Ministry of Education, School of Mineral Processing and Bioengineering, Central SouthUniversity, Changsha 410083, China | whitewolf1101@qq.com |
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| 中文摘要: |
| 为了对云南某厂废水中的铂族金属Pt(Ⅳ)、Pd(Ⅱ)进行吸附回收，将大肠杆菌E.coli做为吸附剂，探讨其在较适工艺条件下的吸附率，并结合Pt(Ⅳ)、Pd(Ⅱ)的纯溶液吸附来探索E.coli对废水中铂族金属的吸附特性。Pt(Ⅳ)、Pd(Ⅱ)纯溶液吸附实验表明，E.coli对两者吸附能力相当，吸附率分别为96.66%、97.68%；而在工业废水中，E.coli对Pt(Ⅳ)的吸附率仅为19.5%，Pd(Ⅱ)的吸附率仍有97.20%。用SPSS软件对工业废水吸附结果进行显著性分析，综合吸附量、吸附率，可认为废水中存在的大量贱金属对Pd(Ⅱ)的吸附没有产生影响，E.coli对Pd(Ⅱ)表现除了较高的选择吸附性；双相Pt(Ⅳ)-Pd(Ⅱ)溶液吸附实验也表现出了相似的结果。可见在Pt(Ⅳ)-Pd(Ⅱ)共存的溶液中，E.coli对Pd(Ⅱ)具有较高选择吸附性。 |
| 英文摘要: |
| To recover the platinum group metal Pt(IV) and Pd(II) in the waste water of a factory in Yunnan Province, the E.coli was used as adsorbent to investigate the adsorption rate under better conditions and adsorption of pure Pt(IV), Pd(II) solution were used to explore the adsorption characteristics of E.coli on the platinum group metals in wastewater. Pure Pt(IV) and Pd(II) solution adsorption experiments showed that two adsorption capacity of E.coli is equal, and the adsorption rate was 96.66% and 97.68% respectively; in industrial wastewater, the adsorption rate of E.coli on Pt(IV) was 19.5%, and the adsorption rate of Pd(II) was still 97.20%. Analysis results of the adsorption results of industrial wastewater using SPSS software showed the adsorption of Pd(II) was not affected by the presence of a large number of base metals in wastewater, and the E.coli shows Pd(II)-selective sorption behavior; the similar results were also demonstrated by Pt(IV)-Pd(II) solution adsorption experiments. In the solution of Pt (IV)-Pd (II), the E.coli has a high Pd(II)-selective adsorption property. |
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