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酰胺萃取铑的研究 |
Study of Rhodium Extracted by N-Butyl Isooctylamide |
Received:July 10, 2015 |
DOI: |
中文关键词: 有色金属冶金 铑 N-正丁基异辛酰胺 溶剂萃取 |
英文关键词: nonferrous metallurgy rhodium N-butyl isooctylamide solvent extraction |
基金项目:转制科研院所创新能力专项资金(2014EG209024)。 |
Author Name | Affiliation | E-mail | ZHAI Buying | National Instrument Functional Materials Engineering Technology Research Centers,Chongqing Materials Research Institute, Chongqing 400700, China | 13500354172@163.com | PAN Xiong | National Instrument Functional Materials Engineering Technology Research Centers,Chongqing Materials Research Institute, Chongqing 400700, China | | WU Baoan | National Instrument Functional Materials Engineering Technology Research Centers,Chongqing Materials Research Institute, Chongqing 400700, China | | HU Wei | National Instrument Functional Materials Engineering Technology Research Centers,Chongqing Materials Research Institute, Chongqing 400700, China | | LUO Fenglan | National Instrument Functional Materials Engineering Technology Research Centers,Chongqing Materials Research Institute, Chongqing 400700, China | | CHEN Xiaojun | National Instrument Functional Materials Engineering Technology Research Centers,Chongqing Materials Research Institute, Chongqing 400700, China | |
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中文摘要: |
在SnCl2-HCl-Rh体系中用N-正丁基异辛酰胺萃取铑,采用正交试验的方法,进行了萃取条件实验。引入萃取率计算公式评价各组优劣,以获得最优实验组。实验证明,选择N-正丁基异辛酰胺浓度为1.5 mol/L、磷酸三丁脂加入量为2 mL、HCl浓度为4 mol/L的条件下,N-正丁基异辛酰胺萃取铑一次萃取率达到99%。 |
英文摘要: |
By the way of orthogonal test, the extraction of rhodium by N-butyl isooctylamide from SnCl2-HCl-Rh system are investigated, introduced extraction rate calculation formula of evaluation of each group, in order to obtain the best experimental group. Experiments show that N-butyl iso- octylamide concentration is 1.5 mol/L, tributyl phosphate for the amount of 2 mL, concentration of HCl for 4 mol/L one-time extraction rate of rhodium was reached 99%. |
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