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| 高效液相色谱法测定乙酰丙酮钌纯度的方法研究 |
| An Analytical Method for Determination of Ruthenium Acetylacetonate with High Performance Liquid Chromatography |
| Received:April 21, 2016 |
| DOI： |
| 中文关键词: 分析化学 高效液相色谱法 乙酰丙酮钌 纯度 |
| 英文关键词: analytical chemistry high performance liquid chromatography (HPLC) ruthenium acetylactonate purity |
| 基金项目:云南省科技厅省院省校项目(2015IB019)、昆明市科技计划项目(2016KJJH059)。 |
| Author Name | Affiliation | E-mail | | JIANG Jing | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | dianaair@126.com | | CHANG Qiaowen | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | YAN Caixian | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | LI Jie | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | QIU Honglian | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | qiuhonglian@ipm.com.cn |
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| 中文摘要: |
| 建立了用高效液相色谱(HPLC)分析乙酰丙酮钌纯度的方法。以C18色谱柱为固定相，以乙腈/水53/47 (V/V)溶液为流动相，检测波长为270 nm，可以获得满足乙酰丙酮钌纯度测定要求的色谱图。在乙酰丙酮钌浓度为0.224~0.318 mg/mL时，线性相关系数(r)为0.9993，测定相对标准偏差(RSD)为0.85%，样品加标回收率为99.13%~101.37%。 |
| 英文摘要: |
| A method has been developed to measure the ruthenium acetylacetonate by a high pressure liquid chromatography. The operating conditions were as follows: a C18 chromatographic column, a mixture of acetonitrile and water (V/V=53/47) as the mobile phase and 40℃ of the column temperature. The detection wavelength was fixed at 270 nm and the injection volume was 10 μL. Under these given operating conditions, the linear range of ruthenium acetylactonate is 0.224~0.318 mg/mL (r=0.9993) with a 0.85% of RSD, and the recovery for standard addition ranges from 99.13%~101.37%. |
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