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| 加压碱溶法从氧化铝基废催化剂中回收钯 |
| Recovery of Palladium from the Alumina-Based Waste Catalysts by Pressurized Alkali Dissolution Method |
| Received:September 01, 2015 |
| DOI： |
| 中文关键词: 有色金属冶金 钯 废催化剂 加压 碱溶 氧化铝 回收 |
| 英文关键词: nonferrous metallurgy palladium spent catalyst high pressure alkali solution aluminum oxide recovery |
| 基金项目:云南省省院省校科技合作项目(2013IB020)。 |
| Author Name | Affiliation | | ZHAO Yu | Sino-Platinum Metals Resources Yimen Co.Ltd., Kunming 651100, China | | WANG Huan | Sino-Platinum Metals Resources Yimen Co.Ltd., Kunming 651100, China | | HE Xiaotang | Sino-Platinum Metals Resources Yimen Co.Ltd., Kunming 651100, China | | WU Xilong | Sino-Platinum Metals Resources Yimen Co.Ltd., Kunming 651100, China | | LI Yong | Sino-Platinum Metals Resources Yimen Co.Ltd., Kunming 651100, China | | LI Zixuan | Sino-Platinum Metals Resources Yimen Co.Ltd., Kunming 651100, China | | LIAO Wei | Kunming Institute of Precious Metals, Kunming 650106, China | | LEI Ting | Kunming Metallurgy College, Kunming 650033, China |
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| 中文摘要: |
| 研究了加压碱溶载体法从氧化铝基含钯废催化剂中回收钯的工艺。在高压釜中，反应温度200℃，压力12 kg/cm2，时间6 h，氧化铝载体的溶解效率大于95%；选择甲酸钠作为抑制剂，可将钯在溶液中的浓度降低至0.0005 g/L以下；富集物经溶解-精炼得到纯度大于99.98%的海绵钯，钯直收率为99.02%。 |
| 英文摘要: |
| The process of recovering palladium from the alumina-based waste catalysts by pressurized alkali dissolution method was studied. At the reaction temperature of 200℃, pressure of 12 kg/cm2, and the reaction time of 6 h in the autoclave, the dissolution efficiency of alumina carrier is more than 95%. With sodium formate as inhibitor, the concentration of palladium in solution can be reduced to less than 0.0005 g/L. By dissolving-refining the purity of sponge palladium could be reached to over 99.98%, and the direct recovery of palladium was 99.02%. |
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