Abstract
无水有机溶剂-氯化铜体系浸出金的研究
Research on the Leaching of Gold in Anhydrous Organic Solvents-Copper Chloride System
Received:January 19, 2016  
DOI:
中文关键词: 有色金属冶金  有机溶剂  氯化铜  浸出    还原
英文关键词: nonferrous metallurgy  organic solvent  CuCl2  leaching  gold  reduction
基金项目:国家自然基金(51474146)、上海市自然基金(14ZR1416900)、上海第二工业大学校重点学科建设项目(XXKZD1602)。
Author NameAffiliationE-mail
ZHAO Yingfan Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China yfz0913@sina.com 
ZHANG Chenglong Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China clzhang@sspu.edu.cn 
WANG Jingwei Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China  
BAI Jianfeng Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China  
YUAN Wenyi Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China  
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中文摘要:
      以单因素实验及正交实验研究了无水CuCl2-N,N-二甲基甲酰胺体系浸出金。在无水CuCl2浓度0.75 mol/L、浸出温度75℃、浸出时间75 min、液固比500:1的优化条件下,金的浸出率可以达到96.6%;浸出液中的金可被蒸馏水还原,得到金单质,常温下加溶液体积80%的蒸馏水,经1.5 h,金的还原率达99.2%。体系对实际物料表现出很好的选择性浸出金的能力。
英文摘要:
      The leaching of gold by CuCl2-DMF system was studied by the single-factor and orthogonal experiments. The leaching rate of gold reached 96.6% under the following optimum conditions: The concentration CuCl2 being 0.75 mol/L, the reaction time of 75 min, the ratio of solid to liquid fixed at 500:1. Meanwhile metallic gold could be recovered by adding distilled water into the leachate. 99.2% of gold was reduced at normal temperature when the reaction time was 1.5 h, and the quantity of distilled water added to the leachate was 80% of the leachate volume. When it came o the selective leaching of gold from actual materials, this system worked well.
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