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无水有机溶剂-氯化铜体系浸出金的研究 |
Research on the Leaching of Gold in Anhydrous Organic Solvents-Copper Chloride System |
Received:January 19, 2016 |
DOI: |
中文关键词: 有色金属冶金 有机溶剂 氯化铜 浸出 金 还原 |
英文关键词: nonferrous metallurgy organic solvent CuCl2 leaching gold reduction |
基金项目:国家自然基金(51474146)、上海市自然基金(14ZR1416900)、上海第二工业大学校重点学科建设项目(XXKZD1602)。 |
Author Name | Affiliation | E-mail | ZHAO Yingfan | Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China | yfz0913@sina.com | ZHANG Chenglong | Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China | clzhang@sspu.edu.cn | WANG Jingwei | Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China | | BAI Jianfeng | Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China | | YUAN Wenyi | Shanghai Polytechnic University, Shanghai Cooperative Centre for WEEE Recycle, Shanghai 201209, China | |
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中文摘要: |
以单因素实验及正交实验研究了无水CuCl2-N,N-二甲基甲酰胺体系浸出金。在无水CuCl2浓度0.75 mol/L、浸出温度75℃、浸出时间75 min、液固比500:1的优化条件下,金的浸出率可以达到96.6%;浸出液中的金可被蒸馏水还原,得到金单质,常温下加溶液体积80%的蒸馏水,经1.5 h,金的还原率达99.2%。体系对实际物料表现出很好的选择性浸出金的能力。 |
英文摘要: |
The leaching of gold by CuCl2-DMF system was studied by the single-factor and orthogonal experiments. The leaching rate of gold reached 96.6% under the following optimum conditions: The concentration CuCl2 being 0.75 mol/L, the reaction time of 75 min, the ratio of solid to liquid fixed at 500:1. Meanwhile metallic gold could be recovered by adding distilled water into the leachate. 99.2% of gold was reduced at normal temperature when the reaction time was 1.5 h, and the quantity of distilled water added to the leachate was 80% of the leachate volume. When it came o the selective leaching of gold from actual materials, this system worked well. |
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