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| 氯桥钌配位聚合物[(C5Me5)RuCl2]n的合成及表征 |
| Synthesis and Characterization of Chloride-bridged Ruthenium [(C5Me5)RuCl2]n Polymer |
| Received:August 16, 2016 |
| DOI： |
| 中文关键词: 有机金属配合物 二氯(五甲基环戊二烯基)合钌(III)聚合物 合成 结构 |
| 英文关键词: organometallic complex dichloro(pentamethylcyclopentadienyl)ruthenium(III) polymer synthesis structure |
| 基金项目:云南省省院省校科技合作项目(2015IB019)、昆明市科技计划项目(2016-1-G-03331)。 |
| Author Name | Affiliation | E-mail | | YAN Caixian | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | ycx19860706@163.com | | LI Jie | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | JIANG Jing | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | CHEN Jialin | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | LIU Weiping | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | CHANG Qiaowen | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | changqiaowen@126.com |
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| 中文摘要: |
| 对一步反应合成二氯(五甲基环戊二烯基)合钌(III)聚合物[(C5Me5)RuCl2]n的方法进行改进，将原料中水合三氯化钌与配体的摩尔比调整为1:1.66，采用氩气保护的无水无氧制备装置，产率达到80%。元素分析、红外光谱(IR)、核磁共振(1H-NMR)的表征结果证实了目标产物结构。 |
| 英文摘要: |
| [(C5Me5)RuCl2]n has been synthesized through one-step reaction. Preparation method has been improved and optimized, thus the productivity was up to 80%, which was higher than reproted values of literature. Structure of the complexes have been represented by the structural analytical methods like elemental analysis, IR, 1H-NMR, then their chemical construction were confirmed finally. |
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