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| 1,5-环辛二烯(乙酰丙酮)铱(I)的合成及结构表征 |
| Synthesis and Characterization of (Acetylacetonato)(1,5-cyclooctadiene)iridium(I) |
| Received:July 01, 2017 |
| DOI： |
| 中文关键词: 有机化学 1,5-环辛二烯(乙酰丙酮)铱(I) 合成 结构 |
| 英文关键词: organic chemistry (acetylacetonato)(1,5-cyclooctadiene)iridium(I) synthesis structure |
| 基金项目:云南省基础研究计划项目(2017FD212)、云南省省院省校科技合作项目(2015IB019)、昆明市科技计划项目(2016-1-G-03331)。 |
| Author Name | Affiliation | E-mail | | HOU Wenming | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | hwm@ipm.com.cn | | LI Yanqiong | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | CHEN Xingfei | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | JIANG Jing | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | | | YAN Caixian | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for ComprehensiveUtilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming 650106, China | ycx19860706@163.com |
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| 中文摘要: |
| 在四氢呋喃介质中，将1,5-环辛二烯氯化铱(I)二聚体([Ir(cod)Cl]2)与乙酰丙酮加热回流，一步合成了1,5-环辛二烯(乙酰丙酮)铱(I) [Ir(acac)(cod)]，产率88.6%。用元素分析、红外光谱(IR)和核磁共振(1H-NMR、13C-NMR)等分析，结果表明产物为目标化合物。 |
| 英文摘要: |
| Ir(acac)(cod) was synthesized in one-step process from [Ir(cod)Cl]2 in tetrahydrofuran by adding Hacac as the anion ligand. The yield was 88.6%. Structure of the complexes have been represented by the structural analytical methods like elemental analysis, 1H-NMR, 13C-NMR, IR, then their chemical construction were confirmed finally. |
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