Abstract
铜捕集法从失效汽车催化剂中回收铂、钯和铑的研究
Recovery of Pt, Pd and Rh from Spent Auto Catalysts by Copper Collection Method
Received:December 27, 2017  
DOI:
中文关键词: 有色金属冶金  铂族金属  铜捕集法  失效汽车催化剂  回收
英文关键词: non-ferrous metallurgy  platinum group metal? copper collection method? spent auto catalyst? recovery
基金项目:国家自然科学基金项目(51504106);云南省科技计划项目(2015DC001、2015FB204、2017FA030)。
Author NameAffiliationE-mail
ZHAO Jiachun Kunming Institute of Precious Metals, State key Laboratory of Advanced Technology of ComprehensiveUtilization of Platinum Metals, Sino-platinum Metals Co. Ltd., Kunming 650106, China zhaojiacuhn@ipm.com.cn 
CUI Hao Kunming Institute of Precious Metals, State key Laboratory of Advanced Technology of ComprehensiveUtilization of Platinum Metals, Sino-platinum Metals Co. Ltd., Kunming 650106, China  
BAO Simin Kunming Institute of Precious Metals, State key Laboratory of Advanced Technology of ComprehensiveUtilization of Platinum Metals, Sino-platinum Metals Co. Ltd., Kunming 650106, China  
TONG Weifeng Kunming Institute of Precious Metals, State key Laboratory of Advanced Technology of ComprehensiveUtilization of Platinum Metals, Sino-platinum Metals Co. Ltd., Kunming 650106, China  
DONG Haigang Kunming Institute of Precious Metals, State key Laboratory of Advanced Technology of ComprehensiveUtilization of Platinum Metals, Sino-platinum Metals Co. Ltd., Kunming 650106, China donghaigang0404@126.com 
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中文摘要:
      采用铜捕集法从失效汽车催化剂中回收铂族金属,重点研究了CaO/SiO2质量比、捕集剂、熔炼温度和时间、以及还原剂对Pt、Pd和Rh回收率的影响。结果表明,在CaO/SiO2=1.05,CuO配比35%~40%,还原剂配比6%,熔炼温度1400℃,熔炼时间5 h的条件下,Pt、Pd和Rh回收率分别为98.2%、99.2%和97.6%。
英文摘要:
      A copper collection method was used to recover platinum group metals from a spent auto catalysts. The influences of CaO/SiO2 weight ratio, collection agent and reductant on Pt, Pd and Rh recoveries were studied. The recovery rates are 98.2%, 99.2% and 97.6% for Pt, Pd and Rh, respectively, when the collection condition is as follows: 1.05 of CaO/SiO2 weight ratio, 35%~40% of CuO ratio, 6% of reductant ratio, 1400℃ of smelting temperature and 5 h of smelting time.
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