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| 染料敏化太阳能电池用钌系光敏化剂研究进展 |
| Recent Research Progress of Ruthenium Sensitizers for Dye-sensitized Solar Cells |
| Received:May 11, 2018 |
| DOI： |
| 中文关键词: 染料敏化太阳能电池 联吡啶钌配合物 光电性能 |
| 英文关键词: dye-sensitized solar cells (DSSCs) bipyridyl ruthenium complexes photoelectric properties |
| 基金项目:国家自然科学基金项目(21861023)云南省应用基础研究项目(2017FB141、2017FD212)。 |
| Author Name | Affiliation | E-mail | | HAN Xu | Kumming Institute of Precious Metals, Kunming 650106, China | 1107914746@qq.com | | LI Jie | Kumming Institute of Precious Metals, Kunming 650106, China | | | YAN Caixian | Kumming Institute of Precious Metals, Kunming 650106, China | | | CHANG Qiaowen | Kumming Institute of Precious Metals, Kunming 650106, China | changqiaowen@126.com | | LIU Weiping | Kumming Institute of Precious Metals, Kunming 650106, China | |
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| 中文摘要: |
| 钌系光敏化剂作为染料敏化太阳能电池(DSSC)敏化剂组件中最重要光敏化剂之一，近年来受到国内外研究人员的重视及研究。其中，以羧酸联吡啶钌配合物为光敏化剂的DSSC器件表现出最好的综合性能。简要介绍了钌系光敏剂的结构，以及其性能的主要影响因素。按照各个光敏化剂的结构，分别阐述了固定配体(含羧基、磺酸基等)和辅助配体(二联吡啶衍生物等)对钌系光敏化剂综合性能的影响，同时给出了对应的各类光敏化剂最新研究进展。 |
| 英文摘要: |
| Ruthenium complexes, as one kind of the most important sensitizers in dye-sensitized solar cells (DSSCs)，have attracted much attention in recent years, and important progress has been made. Bipyridyl ruthenium complexes display excellent performance and are being used as sensitizers for DSSCs. In this paper, the effects of the anchoring groups and ancillary ligands on both the photoelectric properties and IPCE of ruthenium complexes are summarized, and several commercialized Ru-based sensitizers with high stability and great efficiency are described. Some new developments are also introduced. |
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