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| (1,5-环辛二烯)氯化钌(II)多聚体的合成及表征 |
| Synthesis and Characterization of Dichloro(1,5-cyclooctadiene)ruthenium(II) Polymer |
| Received:August 22, 2018 |
| DOI： |
| 中文关键词: (1,5-环辛二烯)氯化钌(II)多聚体 合成 表征 |
| 英文关键词: dichloro(1,5-cyclooctadiene)ruthenium(II) polymer synthesis characterization |
| 基金项目:云南省基础研究计划项目(2017FD212, 2017FB141)、云南省省院省校科技合作项目(2015IB019)。 |
| Author Name | Affiliation | E-mail | | YAN Tingxi | Yunnan Tin Co.Ltd., Datun Tin Mine, Honghe 661021, Yunnan, China | yantingxi1981@163.com | | ZHAO Jing | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | | | LI Jie | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | | | LIU Weiping | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | | | YAN Caixian | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | ycx19860706@163.com |
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| 中文摘要: |
| 在无水乙醇介质中，将水合三氯化钌与1,5-环辛二烯加热回流，一步合成了(1,5-环辛二烯)氯化钌(II)多聚体[Ru(cod)Cl2]n，产率96%。用元素分析、核磁共振(1H-NMR、13C-NMR)和红外光谱(IR)等分析表明产物为目标化合物。 |
| 英文摘要: |
| [Ru(cod)Cl2]n was synthesized in one-step process from RuCl3.3H2O in alcohol by adding 1,5-cyclooctadiene as the anion ligand. The yield was 96%. Structure of the complexes have been represented by the structural analytical methods like elemental analysis, 1H-NMR, 13C-NMR, IR, then their chemical construction were confirmed finally. |
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