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| [Ir(ppy)2(dcbpy)]PF6的合成、表征及光物理性能研究 |
| Synthesis, Characterization and Light-physical Property of [Ir(ppy)2(dcbpy)]PF6 |
| Received:August 20, 2018 |
| DOI： |
| 中文关键词: 六氟磷酸二(2,2'-联吡啶).(4,4'-二羧基-2,2'-联吡啶)合铱(III) 合成 晶体结构 光物理性能 |
| 英文关键词: Ir(2,2'-bipyridine)2(4,4'-dimethyl-2,2'-bipyridine)(PF6) synthesis crystal structure light- physical property |
| 基金项目:云南省基础研究计划项目(2017FD212, 2017FB141)、国家自然科学基金(21861023) |
| Author Name | Affiliation | E-mail | | YAN Caixian | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | ycx19860706@163.com | | YAN Tingxi | Datun Tin Mine, Yunnan Tin Co.Ltd., Honghe 661021, Yunnan, China | | | LI Jie | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | | | JIANG Jing | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | | | LIU Weiping | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | | | CHEN Li | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies forComprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co.Ltd., Kunming 650106, China | |
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| 中文摘要: |
| 以氯桥二聚体(ppy)2Ir(μ-Cl2)Ir(ppy)2、4,4'-二羧基-2,2'-联吡啶和六氟磷酸铵为原料合成了一种阳离子型铱配合物[Ir(ppy)2(dcbpy)]PF6，产率94.9%。并通过元素分析、质谱、红外光谱以及核磁共振谱表征确认了目标产物的分子结构。以溶剂缓慢挥发法培养出配合物单晶，经X射线单晶衍射仪表征、计算，获得了晶体结构参数。紫外-可见吸收光谱和光致发光光谱的研究表明，该配合物常温最大发射位于582 nm处，显示发射强烈的黄光。 |
| 英文摘要: |
| A new chemical technique was developed for batch synthesis of ionic iridium(Ⅲ) complex [Ir(ppy)2(dcbpy)]PF6, an organometallic light-emitting molecule for OLED. The first synthetic step was the cycometalation of chloride-bridged dimer (ppy)2Ir(μ-Cl2)Ir(ppy)2 with 4,4'-dimethyl-2,2'-bipyridine, followed by adding hexafluorophosphate acid to produce the desired compound in a batch scale. The yield was more than 94.9%. The chemical structure of [Ir(ppy)2(dcbpy)]PF6 was verified by elemental analysis, FT-IR, NMR (1H and 13C) and MS. Photophysical property of the complex was investigated. Single crystals of complex was prepared by means of the solvent evaporation method and subjected to X-ray diffraction analysis. The yellow-emission at room temperature peaked at 582 nm. |
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