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| 一种新型三氮唑铱(Ⅲ)配合物的合成和表征 |
| Synthesis and characterization of a novel triazole iridium(Ⅲ) complex |
| Received:July 22, 2021 |
| DOI： |
| 中文关键词: 铱(Ⅲ)配合物 三氮唑 乙酰丙酮 合成 晶体结构 |
| 英文关键词: iridium(Ⅲ) complex triazole acetylacetone synthesis crystalline structure |
| 基金项目:国家自然科学基金(21861023)；云南省基础研究计划重点项目(2019FA047)；云南省转制科研院所技术开发研究专项(202004AR040001) |
| Author Name | Affiliation | E-mail | | WANG Zi-ao* | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Precious Metals,Kunming Institute of Precious Metals, Kunming 650106, China | wangza.bb@foxmail.com | | CHEN Hong-lai* | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Precious Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | CHEN Zhu-an* | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Precious Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | YAN Cai-xian* | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Precious Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | JIANG Jing* | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Precious Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | YU Juan* | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Precious Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | LIU Wei-ping* | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Precious Metals,Kunming Institute of Precious Metals, Kunming 650106, China | | | CHANG Qiao-wen* | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Precious Metals,Kunming Institute of Precious Metals, Kunming 650106, China | |
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| 中文摘要: |
| 以5-(4-氟苯基)-1,3-二甲基-1H-1,2,4-三唑(fdpt)为环金属配体、乙酰丙酮(Hacac)为辅助配体合成出一种新型铱(Ⅲ)配合物Ir(fdpt)2(acac)。采用元素分析、红外光谱、核磁共振谱分析和单晶X衍射对其组成和化学结构进行了表征。结果表明，该配合物化学组成为C25H25F2IrN6O2，属于单斜晶系，P21/c空间群。晶胞参数为a=1.58917(14) nm，b=1.64798(15) nm，c=1.06146(9) nm，β=94.741(3)°，V=2.7704(4) nm3，Z=4。 |
| 英文摘要: |
| A new iridium (Ⅲ) complex Ir(fdpt)2(acac) was synthesized with 5-(4-fluorophenyl)-1,3- dimethyl-1H-1,2,4-triazole (fdpt) as the ring metal ligand and acetylacetone (Hacac) as the auxiliary ligand. Its composition and chemical structure were characterized by elemental analysis, IR, NMR and single crystal X-ray diffraction. The result show that that chemical composition of the complex is C25H25F2IrN6O2, which belongs to monoclinic system and P21/c space group. The unit cell parameter is a=1.58917(14)nm, b=1.64798(15)nm, c=1.06146(9)nm, β=94.741(3)°, V=2.7704(4)nm3, Z=4。 |
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