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| 铱配合物(Ir(ppy)2(SFO))的合成及结构表征 |
| Synthesis and structural characterization of iridium complex Ir(ppy)2(SFO) |
| Received:August 20, 2021 |
| DOI： |
| 中文关键词: 铱配合物 合成 表征 |
| 英文关键词: iridium complex synthetic structural characterization |
| 基金项目: |
| Author Name | Affiliation | E-mail | | HOU Wen-liang* | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Sino-Platinum Metals Chemical Yunnan Co. Ltd, Kunming 650106, China | hwl@ipm.com.cn | | ZHAO Fei* | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Sino-Platinum Metals Chemical Yunnan Co. Ltd, Kunming 650106, China | | | CHEN Hong-lai* | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Sino-Platinum Metals Chemical Yunnan Co. Ltd, Kunming 650106, China | | | XU Ming-ming* | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Sino-Platinum Metals Chemical Yunnan Co. Ltd, Kunming 650106, China | | | LI Yong-qing* | Kunming Institute of Precious Metals, State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Sino-Platinum Metals Chemical Yunnan Co. Ltd, Kunming 650106, China | |
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| 中文摘要: |
| 在乙二醇单乙醚介质中，将二聚体Ir2(μ-Cl2)(ppy)4和辅助配体2-噻吩甲酰三氟丙酮(SFO)在碱性条件下，加热回流反应，一步生成了铱配合物Ir(ppy)2(SFO)，产率85.2%。采用核磁共振(1H-NMR、13C-NMR)和质谱等分析表明产物为目标配合物。 |
| 英文摘要: |
| The iridium complex Ir(ppy)2(SFO) was synthesized in one step by heating the dimer Ir2(μ-Cl2)(ppy)4 and the auxiliary ligand SFO under alkaline conditions in ethylene glycol monoethyl ether medium with a yield of 85.2%. The chemical structure of Ir(ppy)2(SFO) was verified NMR (1H and 13C) and MS. |
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