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| 一种三(三苯基膦)二氯化钌的批量制备方法 |
| Batch synthesis of ruthenium(Ⅱ)-tris(triphenylphosphine) dichloride |
| Received:July 17, 2023 |
| DOI： |
| 中文关键词: 三(三苯基膦)二氯化钌 合成 批量 |
| 英文关键词: ruthenium(Ⅱ)-tris(triphenylphosphine) dichloride synthesis batch |
| 基金项目:云南贵金属实验室科技计划项目(YPML-2023050217)；云南省技术创新人才培养项目(202205AD160053)；云南省金属有机分子材料与器件重点实验室(202205AG070004) |
| Author Name | Affiliation | | XU Mingming | Sino-Platinum Metals Chemical Yunnan Co. Ltd., State Key Laboratory of AdvancedTechnologies for Comprehensive Utilization of Platinum Metals, Kunming 650106, China | | HUANG Guangying | Sino-Platinum Metals Chemical Yunnan Co. Ltd., State Key Laboratory of AdvancedTechnologies for Comprehensive Utilization of Platinum Metals, Kunming 650106, China | | ZHANG Ke | Sino-Platinum Metals Chemical Yunnan Co. Ltd., State Key Laboratory of AdvancedTechnologies for Comprehensive Utilization of Platinum Metals, Kunming 650106, China | | HOU Wenliang | Sino-Platinum Metals Chemical Yunnan Co. Ltd., State Key Laboratory of AdvancedTechnologies for Comprehensive Utilization of Platinum Metals, Kunming 650106, China | | TAO Qiaoping | Sino-Platinum Metals Chemical Yunnan Co. Ltd., State Key Laboratory of AdvancedTechnologies for Comprehensive Utilization of Platinum Metals, Kunming 650106, China | | YAN Caixian | Sino-Platinum Metals Chemical Yunnan Co. Ltd., State Key Laboratory of AdvancedTechnologies for Comprehensive Utilization of Platinum Metals, Kunming 650106, China |
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| 中文摘要: |
| 以水合三氯化钌和三苯基膦作为原料，在氩气保护下，甲醇做溶剂，批量合成出了一种三(三苯基膦)二氯化钌。通过优化合成原料的摩尔比例，反应时间，得到最佳批量制备方法，并采用元素分析、核磁共振谱和红外光谱表征了它的化学结构。本合成方法操作简单，产率高，适合批量化生产。 |
| 英文摘要: |
| A new ruthenium (triphenylphosphine) dichloride was synthesized by using hydrated ruthenium trichloride and triphenylphosphine as raw materials under the protection of argon gas and methanol as solvent. The optimum batch preparation method was obtained by optimizing the molar ratio and reaction time of the synthetic material. The chemical structure of the synthetic material was characterized by elemental analysis, nuclear magnetic resonance spectroscopy and infrared spectroscopy. The synthesis method has the advantages of simple operation and high yield, and is suitable for mass production. |
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