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| 双核羧酸铑(Ⅱ)催化反应的研究进展 |
| Research progress in catalytic reactions of binuclear carboxylic acid rhodium(Ⅱ) |
| Received:August 08, 2023 |
| DOI： |
| 中文关键词: 双核羧酸铑(Ⅱ) 催化 研究进展 反应机理 |
| 英文关键词: binuclear rhodium carboxylate(Ⅱ) catalyze research progress reaction mechanism |
| 基金项目:云南省基础研究专项-重点项目(202101AS070049)；云南贵金属实验室科技计划项目(YPML-2022050232，YPML-2023050215) |
| Author Name | Affiliation | | NI Wenruo | Yunnan Precious Metals Laboratory Co.Ltd., Kunming 650106, China
State Key Laboratory of Advanced Technologiesfor Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | | TIAN Yiran | Yunnan Precious Metals Laboratory Co.Ltd., Kunming 650106, China | | LI Hongpeng | Yunnan Precious Metals Laboratory Co.Ltd., Kunming 650106, China | | PI Xiaolin | Yunnan Precious Metals Laboratory Co.Ltd., Kunming 650106, China | | LI Xinyuan | State Key Laboratory of Advanced Technologiesfor Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China | | ZHANG Zhenqiang | Yunnan Precious Metals Laboratory Co.Ltd., Kunming 650106, China |
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| 中文摘要: |
| 双核羧酸铑(Ⅱ)凭借其高稳定性、高化学选择性以及高催化活性等优点在催化、生物制药等诸多领域得到广泛应用。本文详细介绍了双核羧酸铑(Ⅱ)催化有机反应的发展历程及研究现状，并对重要的催化反应及其机理进行总结归纳，旨在为后续的研究提供参考。同时，结合时代发展和产业界的诉求对未来双核羧酸铑(Ⅱ)催化剂的努力方向提出了展望。 |
| 英文摘要: |
| Binuclear rhodium carboxylate(Ⅱ) has been widely used in various fields such as catalysis and biopharmaceuticals due to its high stability, chemical selectivity, and catalytic activity. This article provides a detailed introduction to the development and research status of organic reactions catalyzed by rhodium(Ⅱ) binuclear carboxylate, and summarizes important catalytic reactions and their mechanisms, aiming to provide reference for future research. At the same time, based on the development of the times and the demands of the industry, the future direction of efforts for the dual core carboxylic acid rhodium(Ⅱ) catalyst is proposed. |
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