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| 一种二氯苯基钌(Ⅱ)二聚体的批量制备方法 |
| Batch synthesis of benzeneruthenium(II) chloride dimer |
| Received:August 27, 2024 |
| DOI： |
| 中文关键词: 二氯苯基钌(Ⅱ)二聚体 合成 批量 |
| 英文关键词: benzeneruthenium(II) chloride dimer synthesis batch |
| 基金项目:云南贵金属实验室科技计划项目(YPML-2023050217，YPML-2022050230，YPML-2023050235) |
| Author Name | Affiliation | | YAN Caixian | Yunnan Precious Metals Lab Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China | | HUANG Guangying | Yunnan Precious Metals Lab Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China | | ZHANG Ke | Yunnan Precious Metals Lab Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China | | YAO Moliuxin | Yunnan Precious Metals Lab Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China | | LI Tianci | Yunnan Precious Metals Lab Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China | | HOU Wenming | Yunnan Precious Metals Lab Co. Ltd., Kunming Institute of Precious Metals, Kunming 650106, China |
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| 中文摘要: |
| 以水合三氯化钌、1,3-环己二烯或1,4-环己二烯为原料，在乙醇和蒸馏水或乙醇的混合溶剂中，搅拌反应，过滤，洗涤，干燥，获得二氯苯基钌(Ⅱ)二聚体，产率为97%。对产品的表征结果证实得到了目标产物。制备方法操作简单、产率高，成本低，可实现批量生产。 |
| 英文摘要: |
| Dichlorophenyl ruthenium(Ⅱ) dimer was obtained by stirring reaction, filtration, washing and drying in ethanol or ethanol and distilled water mixture with ruthenium trichloride, 1,3-cyclohexadiene or 1,4-cyclohexadiene as raw materials. The characterization of the product confirmed that the target product was obtained. The preparation method has the advantages of simple operation, high yield and low cost, and can realize mass production. |
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