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| 钌、铱催化剂在电解水制氢OER反应中的研究进展 |
| Research progress of ruthenium and iridium catalysts for the OER reaction involved in hydrogen production from water electrolysis |
| Received:May 29, 2024 |
| DOI： |
| 中文关键词: 电解水制氢 析氧反应(OER) 钌催化剂 铱催化剂 |
| 英文关键词: hydrogen production by electrolysis of water oxygen evolution reaction (OER) ruthenium catalyst iridium catalyst |
| 基金项目: |
| Author Name | Affiliation | | MA Jianji | National Nickel and Cobalt Advanced Materials Engineering Research Center,Lanzhou Jinchuan Technology Park Co. Ltd., Lanzhou 730101, China | | TANG Pengjun | National Nickel and Cobalt Advanced Materials Engineering Research Center,Lanzhou Jinchuan Technology Park Co. Ltd., Lanzhou 730101, China | | ZHANG Jiale | National Nickel and Cobalt Advanced Materials Engineering Research Center,Lanzhou Jinchuan Technology Park Co. Ltd., Lanzhou 730101, China | | ZHANG Jing | National Nickel and Cobalt Advanced Materials Engineering Research Center,Lanzhou Jinchuan Technology Park Co. Ltd., Lanzhou 730101, China | | MA Qian | National Nickel and Cobalt Advanced Materials Engineering Research Center,Lanzhou Jinchuan Technology Park Co. Ltd., Lanzhou 730101, China | | YANG Xiaoyan | National Nickel and Cobalt Advanced Materials Engineering Research Center,Lanzhou Jinchuan Technology Park Co. Ltd., Lanzhou 730101, China |
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| 中文摘要: |
| 电解水制氢是最环保、最有前景的氢气生产方式之一；电解水过程中涉及的析氧反应(OER)是决定电解水制氢速率的重要反应过程。Ru、Ir基催化剂及其合成物是目前为止最有效的电催化剂，可降低OER的高过电势，加快OER反应速度。综述了近年来电解水制氢OER反应中所用到的钌、铱基催化剂及其合成物的设计及合成研究成果，对催化剂的合成思路进行了探讨，对OER反应机制进行了介绍。介绍了Ru(Ir)单质催化剂、铂族金属-Ru(Ir)催化剂和非铂族金属-Ru(Ir)催化剂的制备和研究进展，指出了OER催化剂的未来发展趋势。 |
| 英文摘要: |
| Water electrolysis is one of the most environmentally friendly and promising ways to produce hydrogen. Oxygen evolution reaction (OER) involved in the process of water electrolysis is an important reaction process that determines the rate of hydrogen production, and Ru- and Ir-based catalysts have been known, by far, the most effective electrocatalysts which can reduce the high overpotential of the OER and accelerate the OER reaction. The research results on the design and synthesis of Ru- and Ir-based catalysts used in this field in recent years are reviewed, including single metal catalysts of Ru and Ir, PGM-Ru and-Ir bimetallic catalysts, and non-PGM-Ru and-Ir bimetallic catalysts. Finally, the future development trend of OER catalysts is prospected. |
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